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81.
This paper is about conditions and processes during the accumulation of the Upper Pleniglacial Middle and Upper Silt Loam complexes at Nagelbeek, Limbourg, a Weichselian stratigraphical type locality. The complexes correlate with Hesbayan and Brabantian loesses in Belgium, formed between 28,000 and 12,400 yrs BP. They are characterized by sediment features (cracks, mass deformations, and cut-and-fill features) that are ascribed to a cryogenic regimen. The main Middle Silt Loam subunit contains contraction cracks deformed and further modified by masswasting. Intra-Upper-Pleniglacial pedogenic intervals are inferred from three greyish bands, from a truncated weathered zone surmounting the Middle Silt Loam, and from an aeolian-cumulic palaeosol at the base of the Upper Silt Loam. Latter two zones and an intervening erosional unconformity were cryogenically reworked, less than 22,000 yrs BP, to form a complex stratigraphical marker-zone: the ‘Horizon à Langues de Nagelbeek’. Morphological variants of the marker-zone are described. The geomorphic evolution of the Nagelbeek upland, from Saalian to Holocene times, is summarized in unconformity maps and a time diagram.  相似文献   
82.
Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m−3, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m−3. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.  相似文献   
83.
Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr2O3 contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al2O3 content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO2 contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).  相似文献   
84.
An eruption on the eastern flank of Piton de la Fournaise volcano started on 16 November, 2002 after 10 months of quiescence. After a relatively constant level of activity during the first 13 days of the eruption, lava discharge, volcanic tremor and seismicity increased from 29 November to 3 December. Lava effusion suddenly ceased on 3 December while shallow earthquakes beneath the Dolomieu summit crater were still recorded at a rate of about one per minute. This unusual activity continued and increased in intensity over the next three weeks, ending with the formation of a pit crater within Dolomieu. Based on ground deformation, measured by rapid-static and continuous GPS and an extensometer, seismic data, and lava effusion patterns, the eruptive period is divided into five stages: 1) slow summit inflation and sporadic seismicity; 2) rapid summit inflation and a short seismic crisis; 3) rapid flank inflation, onset of summit deflation, sporadic seismicity, accompanied by stable effusion; 4) flank inflation, coupled with summit deflation, intense seismicity, and increased lava effusion; and finally 5) little deflation, intense shallow seismicity, and the end of lava effusion. We propose a model in which the pre-intrusive inflation of Stage 1 in the months preceding the eruption was caused by a magma body located near sea level. The magma reservoir was the source of an intrusion rising under the summit during Stage 2. In Stage 3, the magma ponded at a shallow level in the edifice while the lateral injection of a radial dike reached the surface on the eastern flank of the basaltic volcano, causing lava effusion. Pressure decrease in the magmatic plumbing system followed, resulting in upward migration of a collapse front, forming a subterranean column of debris by faulting and stoping. This caused intense shallow seismicity, increase in discharge of lava and volcanic tremor at the lateral vent in Stage 4 and, eventually the formation of a pit crater in Stage 5.  相似文献   
85.
研究了铜精矿催化加压浸取净化除铁后 ,料液中铜镍的萃取分离及串级模拟实验。采用LIX984萃取剂 ,在料液 pH =4.0时铜镍分离效果较为理想。除铜后的料液 ,用P2 0 4 萃取富集镍。经硫酸反萃的溶液可直接用于铜镍的电解精炼。  相似文献   
86.
报道了新显色剂2-(2-苯并噻唑偶氮)-5-二羧甲氨基苯甲酸(BTACB)的合成,研究了在十二烷基硫酸钠(NaLS)存在下Ni~(2+)与BTACB形成蓝紫色配合物的条件,其λ_(max)~(MR)=600nm,ε=2.79×10~4L·mol~(-1)·cm~(-1),Ni在0~0.6μg/ml范围内服从比尔定律,反应具有一定的选择性。方法已用于直接测定铝合金、纯镁及含一定量Co的钢铁中痕量Ni和经萃取分离后测定纯钴中痕量Ni。  相似文献   
87.
The atmosphere and the ocean are subject to many dynamical instabilities, which limit the time during which their behaviour can be deterministically forecasted. At longer timescales, the atmosphere can be predicted at best using statistical methods, as a response to external forcing linked to sea- and land-surface anomalies. Climate being defined as the mean of atmospheric states, it appears that it can be predicted up to a few months in advance, which is the characteristic time of the so-called slow components of the climate system. Forecasting can sometimes be extended to longer time ranges, especially when the coupled ocean–atmosphere system exhibits internal variability modes, with characteristic times of a few years. Seasonal climate forecasting is most often based upon Monte-Carlo simulations, where the various realisations correspond to slightly different initial conditions. The present sate-of-the-art in Europe (ECMWF) and/or in the USA (IRI) allows to forecast such major phenomena, as El Niño, up to six months in advance. Finally, some parameters may exhibit predictability at still longer time-ranges (inter-annual to decadal), but only for certain regions. The example of electricity production is used to underline the potentially large economical benefit of seasonal climate forecasting. To cite this article: J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.

Résumé

L'atmosphère et l'océan sont le siège d'instabilités dynamiques, qui limitent la durée pendant laquelle il est possible d'en prévoir l'évolution de façon déterministe. Au-delà, l'atmosphère n'est plus prévisible, au mieux, que de façon statistique, en fonction du forçage externe qu'exerce(nt) sur elle l'océan et/ou la surface des continents. Le climat (au sens d'une moyenne des états atmosphériques) se révèle ainsi prévisible jusqu'à des échéances temporelles de quelques mois, échelle de temps caractéristique des composantes dites « lentes » du système climatique. La prévision peut s'étendre à des échéances parfois plus longues, dans le cas où le système couplé océan–atmosphère posséderait des modes de variabilité temporelle de périodes caractéristiques de quelques années. La prévision climatique saisonnière est très souvent construite à partir de simulations de type Monte-Carlo, avec des ensembles de réalisations utilisant des conditions initiales légèrement différentes. Dans l'état actuel de ces prévisions, qu'elles soient réalisées en Europe (CEPMMT) ou aux États-Unis (IRI), il est possible de prévoir environ six mois à l'avance un certain nombre de phénomènes climatiques, en particulier ceux liés aux épisodes dits « El Niño », pour lesquels l'amplitude des variations est suffisamment importante. Il existe, par ailleurs, une prévisibilité à encore plus longue échéance (inter-annuelle à décennale), mais seulement pour certains paramètres et certaines régions. L'exemple de la production d'électricité montre l'importance économique potentielle très grande de la prévision climatique saisonnière. Pour citer cet article : J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.  相似文献   
88.
In southwest Niger, the Continental Terminal water table displays a natural hollow shape about 10 m in depth over an area of 4000 km2. A 10-year survey of this hollow aquifer has shown that current recharge is above 20 mmyr?1. The water table has risen continuously since the 1950–1960s as a result of land clearance. This shows a disequilibrium in the aquifer balance. The long-term recharge rate is estimated by radioisotopes to be around mmyr?1. This figure fits with the only possible origin of the piezometric depression, i.e. evapotranspiration losses in its centre. To cite this article: G. Favreau et al., C. R. Geoscience 334 (2002) 395–401.  相似文献   
89.
阿尔泰地区存在 5条与深大断裂有关的基性、超基性岩带 ,是铜镍硫化物矿床产出的有利地段 ,其中喀拉通克铜镍矿是我国大型铜镍矿之一。通过对成矿必要条件的深入研究 ,得出深大断裂及其次级断裂控制了岩体的产出 ,北北西向断裂叠加北西向断裂控制了矿体的产出 ;成矿充分条件是基性、超基性岩体 ,总结了岩体含矿性的评价指标。结合重磁及地化资料 ,在喀拉通克铜镍矿的成矿模式基础上 ,建立了区域综合信息找矿模型 ,进行成矿预测 ,圈定靶区 9处。  相似文献   
90.
合成了1-(4-硝基苯基)-3-(3,5-二溴吡啶)三氮烯(NPDBPDT),并研究了NPD-BPDT与镍的显色反应。在pH 10.0的Na2B4O7-NaOH缓冲溶液介质中,表面活性剂Triton X-100存在下,镍与试剂生成摩尔比为1∶4的络合物在470 nm处有最大正吸收峰,表观摩尔吸光系数为1.02×105L.mol-1.cm-1;在540 nm处有最大负吸收峰,表观摩尔吸光系数为1.15×105L.mol-1.cm-1;以540 nm为参比波长、470 nm为测量波长进行双波长测定,表观摩尔吸光系数为2.17×105L.mol-1.cm-1。镍含量在0~480μg/L内符合比尔定律。方法用于合金样品中镍的测定,结果与原子吸收法相符,加标回收率为98.0%~102.0%;精密度小于5%(RSD,n=6)。  相似文献   
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